Export Mailbox to PST
From KlavoWiki
To export the contents of a mailbox to a PST use the command below. The maxium file size is 50 GB. The share you are writing to must allow the group Exchange Trusted Subsystem read/write access.
Microsoft New-MailboxExportRequest
New-MailboxExportRequest -Mailbox username -FilePath \\server\share\filename.pst
To verify the status of the move request.
Get-MailboxExportRequest | fl identity, status
Clear the export request
Remove-MailboxExportRequest -Identity "ingrnet.com/Asia Pacific/Australia/Brisbane/Users/Wiggins, Simon R\MailboxExport"